Hexaalkylcyclotrisilanes (R2Si) 3: hexakis (1-ethylpropyl) and hexaisopropyl derivatives

S Masamune, H Tobita, S Murakami

文献索引：Masamune,S.; Tobita,H.; Murakami,S. Journal of the American Chemical Society, 1983 , vol. 105, p. 6524

被引用次数: 53

摘要

Hexakis (2, 6-dimethylphenyl) cyclotrisilane (1) l represents the first and thus far only compound that incorporates the silicon three-membered ring system. While the strain imposed upon this small ring is clearly and uniquely manifested in its chemical behavior, the full aryl substitution in 1 causes significant perturbation of the electronic structure intrinsic to the cyclotrisilane system2 With the purpose of eliminating this complication, the synthesis ...