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Vibrational spectra and rotational isomerism of 1, 2-dimethyldisilane

K Ohno, M Hayashi, H Murata

文献索引:Ohno, Keiichi; Hayashi, Michiro; Murata, Hiromu Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1983 , vol. 39, # 4 p. 373 - 382

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被引用次数: 6

摘要

Abstract The ir and Raman spectra of 1, 2-dimethyldisilane and its Si-perdeuterated species have been measured for the liquid and solid states. Existence of rotational isomers about the Si Si bond was shown on the basis of the spectral examination and the normal coordinate treatment. The fundamental vibrations were assigned for the two possible rotational isomers.