The Influence of Arylene and Alkylene Units on the Structuring of Urea??Based Bridged Silsesquioxanes
…, C Bied, JJE Moreau, M Wong Chi Man
文献索引:Pichon, Benoet P.; Scampini, Sylvana; Bied, Catherine; Moreau, Joel J. E.; Wong Chi Man, Michel European Journal of Inorganic Chemistry, 2012 , # 32 p. 5312 - 5322
Abstract The influence of the intrinsic self-assembling properties of rigid or semirigid aromatic units as the main substructures combined with the effect of the alkylene side chains as linkers on the nanostructure of bridged silsesquioxanes was studied. The symmetry of the organic units was found to control the dimensionality of the hybrid nanostructure. Bis (silylated) aromatic units lead to lamellar hybrids, whereas tris (silylated) aromatic units ...