Redox-active monolayers in mesoporous silicon

…, N Darwish, PJ Reece, JJ Gooding

文献索引：Ciampi, Simone; James, Michael; Le Saux, Guillaume; Gaus, Katharina; Justin Gooding Journal of the American Chemical Society, 2012 , vol. 134, # 2 p. 844 - 847

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被引用次数: 9

摘要

Herein, redox reactions at chemically derivatized porous silicon (PSi) films are investigated. Passivation of the PSi matrix, by replacing metastable Si–H termini with nonpolar Si C C R linkages, allows the electrochemical PSi device to operate in aqueous environments under oxidizing conditions (ie, electron hole accumulation regime). Cu (I)-catalyzed alkyne– azide cycloaddition reactions are used to anchor ferrocene derivatives and probe ...