Journal of the American Chemical Society

Free-radical rearrangement of a silyl radical via net 1, 2-migration of an acetoxy group

JW Wilt, SM Keller

文献索引：Wilt, James W.; Keller, Steven M. Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1395 - 1396

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被引用次数: 10

摘要

We report here the first positive ESR identification of a neutral mixed triatomic transition-metal cluster, CuAgCu, which has been produced at 77 K by cocondensing 63Cu atoms ( I = 3/2), Io7Ag (I = atoms, and C6D6 on the cold surface of a rotating cryo ~ tat . ~ ~ ~ Isotopically pure silver (98.22% 107Ag)9 and copper (98.89% 63Cu)9 were chosen for these experiments because of the anticipated complexity of the spectra from natural copper and silver. The EPR ...