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Tetrahedron letters

First total synthesis of (−)-α-conidendrin

P Boissin, R Dhal, E Brown

文献索引:Boissin, Patrick; Dhal, Robert; Brown, Eric Tetrahedron Letters, 1989 , vol. 30, # 33 p. 4371 - 4374

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被引用次数: 15

摘要

Abstract Regioselective introduction of a benzoxy group, in the benzylic position of the β- benzyl-γ-butyrolactone (R)-(+)-8, was achieved by tretment with NBS followed with benzyl alcohol. α-Alkylation of the lithium enolate of the resulting intermediate 11, with Full-size image (< 1 K)