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Journal of the American Oil Chemists' Society

Synthesis of a fatty tetrahydroxyamide using peroxygenase from oat seeds

GJ Piazza, TA Foglia

文献索引:Piazza, George J.; Foglia, Thomas A. JAOCS, Journal of the American Oil Chemists' Society, 2004 , vol. 81, # 10 p. 933 - 937

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被引用次数: 4

摘要

Abstract Prior work has shown that oat (Avena sativa) seeds are a rich source of lipase and peroxygenase. Partial epoxidation of the isobutyl amide derivative of α-linolenic acid with peroxygenase gave Ni-butyl-9, 10–15, 16-diepoxy-12 (Z)-octadecenamide, a diepoxide product in which the epoxides reside only at the formerly external double bond positions. No amide hydrolysis occurred during the epoxidation procedure. Hydrolysis of the diepoxide ...