Rearrangement of allylic azides

A Gagneux, S Winstein, WG Young

文献索引：Gagneux,A. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 5956 - 5957

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被引用次数: 113

摘要

A mixture of a, a-dimethylallyl and y, y-dimethylallyl azides may be obtained from treatment of y, y-dimethylallyl chloride with a solution of sodium azide in aqueous acetone. This mixture, bp 26-39'(40 mm.), has the correct C, H-analysis and displays an infrared band at 2140 cm.-l, characteristic of azides. 2 A mixture of a-and y-methylallyl azides, bp 64-72'(300 mm.), with the correct C, H-analysis is obtained analogously from trans-crotyl chloride. By ...