Synthesis and Stereochemistry of 1-oxa-6-heteraspiro [2.5] octanes. Single-crystal analysis of 6-phenyl-1-oxa-6-phosphaspiro [2.5] octane 6-sulfide

N Satyamurthy, KD Berlin, MB Hossain…

文献索引：Satyamurthy, Nagichettiar; Berlin, K. Darrell; Hossain, M. Bilayet; Helm, Dick van der Phosphorus and Sulfur and the Related Elements, 1984 , vol. 19, p. 113 - 130

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被引用次数: 4

摘要

Abstract The synthesis of several 1-oxa-6-heteraspiro [2.5] octanes is reported herein for the first time. Stereochemical analysis via NMR studies and a single crystal X-ray diffraction analysis of 6-phenyl-1-oxa-6-phosphaspiro [2.5] octane 6-sulfide have been completed and provide the basis for correlations of structures for other members of the families yet unknown. Epoxidation of cis-2, 6-diphenyl-4-thianone with dimethyl-oxosulfonium ...