A synthesis of N-alkyl and N, N-dialkyl O-ethyl thiocarbamates from diethyl dixanthogenate using different oxidants

MM Milosavljević, M Sovrlić, AD Marinković…

文献索引：Milosavljevic, Milutin M.; Sovrlic, Milica; Marinkovic, Aleksandar D.; Milenkovic, Dragan D. Monatshefte fur Chemie, 2010 , vol. 141, # 7 p. 749 - 755

全文：HTML全文

被引用次数: 10

摘要

Abstract A novel synthesis of N-alkyl and N, N-dialkyl O-ethyl thiocarbamates from diethyl dixanthogenate and primary and secondary amines, using three oxidizing systems, has been developed on the laboratory scale, and the method using sodium hypochlorite has been applied on a semi-industrial scale. The effect of the oxidizing agents, sodium hypochlorite, in-situ-generated peracetic acid, and the manganese (II) acetate/oxygen ...