Hydroformylation of fluoro olefins, RfCH: CH2, catalyzed by group VIII transition-metal catalysts. Crucial factors for extremely high regioselectivity

…, K Kato, M Okabe, T Fuchikami

文献索引：Ojima, Iwao; Kato, Koji; Okabe, Masami; Fuchikami, Takamasa Journal of the American Chemical Society, 1987 , vol. 109, # 25 p. 7714 - 7720

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被引用次数: 58

摘要

Abstract: Hydroformylations of fluoro olefins, trifluoroprop-1-ene (TFP), pentafluorobut-1-ene (PFB), heptafluoropent-1-ene (HPFP), heptadecafluorodec-1-ene (HPDFD), vinyl fluoride (VF), pentafluorostyrene (PFS), and allylpentafluorobenzene (4a), promoted by transition- metal catalysts were studied. Remarkable dependency of the regioselectivity of the reaction on the catalyst metal species (Co, Pt, Ru, and Rh) was found in the reactions of TFP and ...