Journal of organometallic chemistry

New rhodium complexes with P, N-ligands possessing a hydroxy or methoxy group. Synthesis, characterization and application to hydroformylation of styrene

ID Kostas, CG Screttas

文献索引：Kostas, Ioannis D.; Screttas, Constantinos G. Journal of Organometallic Chemistry, 1999 , vol. 585, # 1 p. 1 - 6

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被引用次数: 47

摘要

Two new cationic rhodium (I) complexes containing a phosphino amino alcohol ligand and a methoxy amino phosphine, respectively, have been prepared. According to IR and NMR data the ligands are P, N-bonded and coordination of the hydroxy or the methoxy group to the metal does not take place. The complexes were applied to the hydroformylation of styrene and displayed a quantitative chemoselectivity for aldehydes with a very good ...