Tetrahedron Letters

A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br 3 CCOOEt/PdCl 2 as the catalyst

P Srithanakit, W Chavasiri

文献索引：Srithanakit, Phatsupha; Chavasiri, Warinthorn Tetrahedron Letters, 2011 , vol. 52, # 19 p. 2505 - 2507

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被引用次数: 5

摘要

Abstract Bromosilanes were prepared conveniently and efficiently via the reaction of hydrosilanes and Br 3 CCOOEt in the presence of a catalytic amount of PdCl 2 in refluxing THF over 15 min in high yields. The developed methodology was further applied for the one- pot synthesis of silyl ethers and silyl esters in excellent yields.