Helvetica Chimica Acta

Etude du Comportement Photochimique de quelques Diaryl??1, 3??triazènes

PM Julliard, G Vernin, J Metzger

文献索引：Julliard, Michel; Vernin, Gaston; Metzger, Jacques Helvetica Chimica Acta, 1980 , vol. 63, # 2 p. 456 - 466

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被引用次数: 12

摘要

Summary The photolysis of Diaryl-1, 3-triazenes gives products whose structures are consistent with a cage recombination process of homolytically formed radicals and subsequent abstraction of hydrogen from the solvent molecules by arylamino radicals. In aromatic solvents, a free-radical chain process leads to the formation of products resulting from the homolytic substitution on the solvent. Quenching experiments show that singlet ...