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Tetrahedron

The synthesis of α-methyl-β-phenylisocysteine and the preparation of substituted thiazolidine-5-carboxylic acids

G Stefanović, A Stojiljković, M Stefanović

文献索引:Stefanovic,G. et al. Tetrahedron, 1962 , vol. 18, p. 413 - 418

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被引用次数: 2

摘要

(A) A new route of α-mercapto-β-amino-α, β-disubtituted carboxylic acids has been presented. By condensing 5-methyl-2-thiothiazolidine-4-one and benzylidene-N, N- bisacetamide, 5-methyl-5-[α-acetylaminobenzyl]-2-thiothiazolidine-4-one was obtained and this was converted through its oxime into the corresponding thiazolidine-2, 4-dione. By the action of alkali the thiazolidine ring was cleaved and α-methyl-β-phenylisocysteine and its ...