Kinetics of the brominated alkyl radical (CHBr2, CH3CHBr) reactions with NO2 in the temperature range 250–480 K

MP Rissanen, AJ Eskola…

文献索引：Rissanen, Matti P.; Eskola, Arkke J.; Timonen, Raimo S. International Journal of Chemical Kinetics, 2012 , vol. 44, # 12 p. 767 - 777

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被引用次数: 4

摘要

Abstract The gas-phase kinetics of CHBr 2+ NO 2 and CH 3 CHBr+ NO 2 reactions have been studied in direct time resolved measurements using a tubular flow reactor coupled to a photoionization mass spectrometer. The radicals were generated by pulsed laser photolysis of bromoform and 1, 1-dibromoethane at 248 nm. The subsequent decays of the radical concentrations were monitored as a function of [NO 2] under pseudo–first-order conditions ...