Synlett

Rapid and reusable copper catalytic system for allylic oxidation of olefins in hexafluoroisopropanol as solvent

F Fache, O Piva

文献索引：Fache, Fabienne; Piva, Olivier Synlett, 2002 , # 12 p. 2035 - 2036

全文：HTML全文

被引用次数: 6

摘要

In a typical procedure, Cu 2 O (0.05 mmol) was mixed with the commercially available perfluorinated acid C 11 F 23 COOH (0.1 mmol) in HFIP (1.5 mL) to ensure its complete solubility. The solution took rapidly a deep blue colour. Olefin (5 mmol) and t-BuOOC(O)Ph (1 mmol) were then ...