Organometallics

Electrophilic substitution with allylic rearrangement (SE') stereochemistry of trifluoroacetolysis of some cyclohex-2-enylmetal compounds

G Wickham, D Young, W Kitching

文献索引：Wickham, Geoffrey; Young, David; Kitching, William Organometallics, 1988 , vol. 7, p. 1187 - 1195

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被引用次数: 26

摘要

Conclusions Knowing how an allyl ligand will bind to an electron deficient (< l&electron) early transition metal and how easily it will undergo q3 to q1 isomerization is important in attempting to understand the reactivity of early-transition-metal allyl complexes. Under what circumstances will an allyl ligand bind q3 versus ql? We have previously shown that the Cp*(allyl) ZrBr, compounds (allyl= 1, 1, 2-trimethylallyl and 1, 2, 3-trimethylallyl) have q3- ...