Click-chemistry-based bis-triazolylpyridine diphosphonate ligand for the sensitized luminescence of lanthanides in the solid state within the layers of γ-zirconium …
E Brunet, O Juanes, L Jiménez, JC Rodríguez-Ubis
文献索引：Brunet, Ernesto; Juanes, Olga; Jimenez, Laura; Rodriguez-Ubis, Juan Carlos Tetrahedron Letters, 2009 , vol. 50, # 38 p. 5361 - 5363
The synthesis by means of 'click'chemistry of a new ligand bearing the bis-triazolylpyridine motif and pendant phosphonate groups is described. The topotactic phosphate/ phosphonate exchange of the ligand into gamma-zirconium phosphate led to an organic– inorganic-layered material which revealed an excellent matrix to achieve the efficient sensitization of emitting lanthanides.
