Journal of the American Chemical Society

Silanones and silanethiones from the reactions of transient silylenes with oxiranes and thiiranes in solution. The direct detection of diphenylsilanethione.

SS Kostina, WJ Leigh

文献索引：Khabashesku, V. N.; Kerzina, Z. A.; Baskir, E. G.; Maltsev, A. K.; Nefedov, O. M. Journal of Organometallic Chemistry, 1988 , vol. 347, p. 277 - 294

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被引用次数: 12

摘要

... Journal of the ... lived transient product exhibiting λ max ≈ 275 nm, which has been assigned to diphenylsilanethione (Ph 2 Si═S) on the basis ... For example, both species typically react rapidly with water and alcohols via net O−H insertion, yet singlet carbenes most commonly do ...