Reaction of (polyfluoroalkyl) trimethylammonium salts with hydroxide ion

H Yamanaka, S Yamashita, K Fukunishi…

文献索引：Yamanaka, Hiroki; Yamashita, Seiji; Fukunishi, Koushi; Kuwabara, Masaki; Ishihara, Takashi; Nomura, Mototeru Journal of Fluorine Chemistry, 1991 , vol. 52, # 2 p. 185 - 194

全文：HTML全文

被引用次数: 8

摘要

Abstract (Polyfluoroalkyl) trimethylammonium iodides (1a–d), R f CF 2 CH 2 N+ Me 3 I−(R f−, a= HCF 2, b= CF 3, c= H (CF 2) 3, d= H (CF 2) 5), reacted easily with an equimolar amount of sodiumhydroxide in water at 20 C to give Z isomers of (polyfluoro-1-alkenyl) trimethylammoniumiodides (2a–d), R f CF CHN+ Me 3 I−, quantitatively. However, treatment of 1 with 3 equimolaramounts of sodium hydroxide yielded different products ...