The Journal of organic chemistry

Photoinduced electron-transfer substitution reactions via unusual charge-transfer intermediates

JB Miller, JR Salvador

文献索引：Miller, John B.; Salvador, James R. Journal of Organic Chemistry, 2002 , vol. 67, # 2 p. 435 - 442

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被引用次数: 13

摘要

The photoinduced substitution reactions of halogenated alkanes (1-haloadamantanes, 1- haloronorbornanes, menthyl chloride) with a homologous series of amines or alcohols (methylamine, 2-methyl-2-aminopropane, methanol, or 2-methyl-2-propanol) to form the corresponding alkane-substituted amines or ethers and HCl were investigated. The geometry of the bridgehead carbons made SN2 reactions impossible. Nonpolar reaction ...