Use of tetramethylthiuram disulfide in synthesis of nitrogen-containing heterocyclic compounds

AM Demchenko, VA Yanchenko, VV Kisly…

文献索引：Demchenko; Yanchenko; Kisly; Lozinskii Chemistry of Heterocyclic Compounds, 2005 , vol. 41, # 5 p. 668 - 672

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被引用次数: 6

摘要

Abstract We have developed a method for synthesis of aryl isothiocyanates by means of thiocarbamoylation of aromatic amines by tetramethylthiuram disulfide followed by degradation of the intermediate N (1)-aryl-N, N-dimethylthiourea by concentrated HCl. We have shown that thiocarbamoylation of 4-amino-5-ethyl-4H-1, 2, 4-triazole-3-thiol occurs at the 2 position of the triazole ring, while thiocarbamoylation of 4-amino-3-methyl-6-phenyl- ...