Asymmetric Hydrogenation of Allylic Alcohols Using Ir–N, P-Complexes

JQ Li, J Liu, S Krajangsri, N Chumnanvej, T Singh…

文献索引：Wang, Quanjun; Liu, Xueying; Liu, Xian; Li, Bin; Nie, Huifang; Zhang, Shengyong; Chen, Weiping Chemical Communications, 2014 , vol. 50, # 8 p. 978 - 980

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摘要

In this study, a series of γ, γ-disubstituted and β, γ-disubstituted allylic alcohols were prepared and successfully hydrogenated using suitable N, P-based Ir complexes. High yields and excellent enantioselectivities were obtained for most of the substrates studied.