Journal of Fluorine Chemistry

(Polyfluoroorganoxyalkyl) trialkoxysilanes

MG Voronkov, NF Chernov, ON Florensova

文献索引：Voronkov, M. G.; Chernov, N. F.; Florensova, O. N. Journal of Fluorine Chemistry, 1985 , vol. 29, p. 74

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摘要

The reaction of (haloalkyl)trialkoxysilanes with polyfluorinated alkoxides is carried out in a similar way. This reaction, however, is accompanied by some side-processes due to which the yield of (polyfluoroalkoxyalkyl)trialkoxysilanes does not exceed 20%. Besides, the products of transetherificcation and SiC bond cleavage are formed. The reaction of (polyfluoroorganoxyalkyl)trialkoxysilanes with triethanolamine leads to the corresponding 1-substituted silatranes, R F O(CH 2 ) n ...