Gold/Acid??Co??catalyzed Direct Microwave??Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides

B Alcaide, P Almendros…

文献索引：Alcaide, Benito; Almendros, Pedro; Quiros, M. Teresa Chemistry - A European Journal, 2014 , vol. 20, # 12 p. 3384 - 3393

全文：HTML全文

被引用次数: 5

摘要

Abstract The gold–acid-co-catalyzed synthesis of nine series of fused azaheterocycles with structural diversity starting from the same synthons as readily available propargylic hydroperoxides and aromatic amines has been achieved. The overall tandem process consists in a gold-catalyzed hydroperoxide rearrangement/Michael reaction followed by a final acid-catalyzed cyclization.