Tetrahedron letters

A synthesis of allylboronates via the palladium (0)-catalyzed cross-coupling reaction of bis (pinacolato) diboron with allylic acetates

T Ishiyama, T Ahiko, N Miyaura

文献索引：Ishiyama, Tatsuo; Ahiko, Taka-Aki; Miyaura, Norio Tetrahedron Letters, 1996 , vol. 37, # 38 p. 6889 - 6892

被引用次数: 121

摘要

The cross-coupling reaction of bis(pinacolato)diboron [(Me 4 C 2 O 2 )BB(O 2 C 2 Me 4 )] with allyl acetates regio- and E-stereoselectively provided the pinacol esters of allylboronic acids in high yields. The reaction was efficiently catalyzed by Pd(dba) 2 in DMSO at 50 °C. ... Cookies are used by this site. To decline or learn more, visit our Cookies page.

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