前往化源商城

Chemistry - A European Journal 2017-09-21

Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides

Eric A. Marro, Eric M. Press, Tapas K. Purkait, Daniel Jimenez, Maxime A. Siegler, Rebekka S. Klausen

文献索引:10.1002/chem.201704217

全文:HTML全文

摘要

This crystallographic and computational study describes an unusual potassium silanide structure. A contact ion pair is expected in the solid state between potassium and silicon, yet the potassium cation binds an aromatic ring and the anionic silanide interacts with CH bonds on neighboring crown ether molecules. These structure-bonding phenomena are attributed to strong soft-soft interactions.