Metal complex electrocatalytic reduction of 1, 1-dihalocyclopropanes

VV Yanilkin, EI Strunskaya, NV Nastapova…

文献索引：Yanilkin; Strunskaya; Nastapova; Maksimyuk; Bredikhina; Sharafutdinova; Bredikhin Russian Chemical Bulletin, 2003 , vol. 52, # 4 p. 923 - 928

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被引用次数: 3

摘要

Abstract Catalytic electroreduction of several substituted gem-dihalocyclopropanes was studied in the presence of metal salen-complexes by polarography, cyclic voltammetry, and preparative electrolysis. Monohalocyclopropanes (54—59%) and the corresponding allene (5—9%) were the main reduction products. The reaction rate constants were determined. The inner-sphere electron transfer was shown to occur under these conditions.