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The Journal of Organic Chemistry

The Decomposition of Spiranone p-Toluene-sulfonylhydrazones. A Convenient Synthetic Route to Spirenes

AP Krapcho, R Donn

文献索引:Krapcho,A.P.; Donn,R. Journal of Organic Chemistry, 1965 , vol. 30, p. 641 - 644

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被引用次数: 11

摘要

The dehydration of a-hydroxyspirans (1) to produce spirenes (2) is djlKcult to perform because of the tendency for carbon skeleton rearrangement to occur in these neopentyl-type systems. 2 In the dehydration of spir0 [4.5] decan-6-01 (1, R= OH; m= 2; n= 3) over ...