Quantitative aspects of radical addition. Part IV. Rate-constant ratios for addition of trichloromethyl and thiyl radicals to olefins

JIG Cadogan, IH Sadler

文献索引：Cadogan,J.I.G.; Sadler,I.H. Journal of the Chemical Society [Section] B: Physical Organic, 1966 , p. 1191 - 1205

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被引用次数: 19

摘要

The factors affecting the rate of addition of free radicals to olefinic double bonds have been examined with special reference to the relative importance of polar, resonance, and steric phenomena. A valid competitive method has been employed to measure the relative reactivities of substituted trans-stilbenes, substituted styrenes, and various aliphatic olefins towards thiyl radicals derived from thioglycollic acid and its methyl ester, and ...