前往化源商城

Platinum??Catalyzed Hydrosilylations of Internal Alkynes: Harnessing Substituent Effects to Achieve High Regioselectivity

DA Rooke, EM Ferreira

文献索引:Rooke, Douglas A.; Ferreira, Eric M. Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3225 - 3230

全文:HTML全文

被引用次数: 58

摘要

The metal-catalyzed hydrosilylation of C–C multiple bonds is a well-studied and effective transformation.[1] Studies concerning catalyst activity, coordination environment, and mechanism have provided substantial insight into the nature of this reaction. Vinylsilanes, the product of the monohydrosilylation of alkynes, have proven to be highly useful synthetic compounds, and versatile reagents in both nucleophilic additions and cross-couplings.[2] ...