Journal of the Chemical Society C: Organic

The reaction of chlorofluoroalkanes with triethyl phosphite

AE Platt, B Tittle

文献索引：Platt,A.E.; Tittle,B. Journal of the Chemical Society [Section] C: Organic, 1967 , p. 1150 - 1152

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被引用次数: 6

摘要

Chlorofluoroalkanes of the type CCl·[CF]· Cl,= 2, 4, 6, etc., when treated with trialkyl phosphites, yield three products; an olefin CCl: CF·[CF]· Cl, an alkyl derivative RCCl·[CF]· Cl and, probably, an alkenylphosphonate (RO) P (O)· CCl: CF·[CF]· Cl. The mechanism of the formation of these products is discussed. The chloro