Electronic control of stereoselectivity. 8. The stereochemical course of electrophilic additions to aryl-substituted 9-isopropylidenebenzonorbornenes

LA Paquette, LW Hertel, R Gleiter…

文献索引：Paquette, Leo A.; Hertel, Larry W.; Gleiter, Rolf; Boehm, Michael C.; Beno, Mark A.; Christoph, Gary G. Journal of the American Chemical Society, 1981 , vol. 103, # 24 p. 7106 - 7121

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被引用次数: 38

摘要

Conclusions Low concentrations of tertiary amines inhibit the liquid-phase autoxidation of cumene by a mechanism which is similar to the one proposed by Russell for inhibition of cumene by tetralin.* Thus they possess the two criteria, high reactivity toward propagation and termination, required by the Russell mechanism. They are extremely reactive in propagation because the transition state for abstraction of an a-hydrogen atom has ...