Laser Flash Photolysis Studies of Oxygen and Sulfur Atom Transfer Reactions from Oxiranes and Thiiranes to Singlet Carbenes1

…, TA Gadosy, J Lusztyk, J Warkentin

文献索引：Pezacki, John Paul; Wood, Paul D.; Gadosy, Timothy A.; Lusztyk, Janusz; Warkentin, John Journal of the American Chemical Society, 1998 , vol. 120, # 34 p. 8681 - 8691

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被引用次数: 38

摘要

Laser flash photolysis (UV-LFP) studies of benzylchlorodiazirine (1a), phenylchlorodiazirine (1b), phenylmethoxydiazirine (1c), 2, 2-dimethoxy-5, 5-dimethyl-Δ3-1, 3, 4-oxadiazoline (6a), 3, 4-diaza-2, 2-dimethoxy-1-oxa [4.3] spirooct-3-ene (6b), 5', 5'-dimethoxyspiro [adamantane]-2, 2'-[Δ3-1, 3, 4-oxadiazoline](6c), and diazofluorene (DAF) in the presence of oxiranes and thiiranes are reported. These compounds, upon irradiation, afford ...