New chiral ligands designed for palladium-catalysed asymmetric allylic alkylation

…, K Kanehira, H Tsuchiya, M Kumada

文献索引：Hayashi, Tamio; Kanehira, Koichi; Tsuchiya, Hiroyoshi; Kumada, Makoto Journal of the Chemical Society, Chemical Communications, 1982 , # 20 p. 1162 - 1164

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被引用次数: 26

摘要

New chiral phosphine ligands containing a chiral functional group remote from the phosphino-groups have been found to be effective in the palladium-catalysed reaction of allyl acetate with the enolate anion of 2-acetylcyclohexanone and give the allylated product in significant enantiomeric enrichment.