Synthesis of a chelating hexadentate ligand with a P 3 N 3 donor set. Crystal and molecular structure of [OC-6-22]-[Co {(RP*, RP*, RP*)-CH 3 C (CH 2 PPhC 6 H 4 NH …
J Bennett, RJ Doyle, G Salem, AC Willis
文献索引：Bennett, Justine; Doyle, Roy J.; Salem, Geoffrey; Willis, Anthony C. Dalton Transactions, 2006 , # 38 p. 4614 - 4622
The first structurally authenticated example of a hexadentate chelating tertiary phosphine in which all six donors are bound to a single metal centre is described. The multidentate ligand (RP*, RP*, RP*)-and (RP*, RP*, SP*)-CH3C (CH2PPhC6H4NH2-2) 3 has been prepared in 80% yield via the reaction of five equivalents of sodium (2-aminophenyl) phenylphosphide (generated in situ from (2-aminophenyl) phenylphosphine and sodium in thf) with 1, 1, 1-tri ...
