Reductive substitution of cobaltocene: displacements of a cyclopentadienyl group on cobaltocene and replacement of same by a diene moiety

DW Slocum, TR Engelmann, RL Fellows…

文献索引：Slocum, D. W.; Engelmann, Theodore R.; Fellows, Robert L.; Moronski, Marek; Duraj, Stan Journal of Organometallic Chemistry, 1984 , vol. 260, # 1 p. C21 - C25

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被引用次数: 7

摘要

Abstract Substitution of a cyclopentadienyl ring of cobaltocene by diene, quinone and cyclopentadienone moieties serves as a synthetic procedure for a series of (η 4-ligand)( cyclopentadienyl) cobalt complexes; some speculation as to the involvement of an η 1- cyclopentadienyl intermediate in these transformations is advanced.