… anomeric effect in the 1, 3-thiazolidines: Evidence for both sulphur and nitrogen as electron donors. Crystal structures of various N-acylthiazolidines including mercury …
S Chandrasekhar, D Chopra, K Gopalaiah…
文献索引：Chandrasekhar, Sosale; Chopra, Deepak; Gopalaiah, Kovuru; Guru Row, Tayur N. Journal of Molecular Structure, 2007 , vol. 837, # 1-3 p. 118 - 131
Evidence for the generalized anomeric effect (GAE) in the N-acyl-1, 3-thiazolidines, an important structural motif in the penicillins, was sought in the crystal structures of N-(4- nitrobenzoyl)-1, 3-thiazolidine and its (2: 1) complex with mercuric chloride, N-acetyl-2- phenyl-1, 3-thiazolidine, and the (2: 1) complex of N-benzoyl-1, 3-thiazolidine with mercuric bromide. An inverse relationship was generally observed between the C2–N and C2–S ...
