The photochemistry of 4-phenyl-1-iodobutane and 4-phenyl-2-iodomethyl-1-butene

JL Charlton, GJ Williams…

文献索引：Charlton, James Leslie; Williams, Gaynor Jane; Lypka, Gerald Nicholas Canadian Journal of Chemistry, 1980 , vol. 58, p. 1271 - 1274

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被引用次数: 16

摘要

The photochemistry of 4-phenyl-1-iodobutane 3 and 4-phenyl-2-iodomethyl-1-butene 4 has been studied to investigate the effect of structure on the character of the intermediates generated on photolysis. The irradiation of the simple primary iodide 3 appears to yield only radical intermediates. By contrast the photolysis of the allylic iodide 4 yields products that are more consistent with cationic intermediates.