Facile Non??Catalyzed Synthesis of Tertiary Phosphine Sulfides by Regioselective Addition of Secondary Phosphine Sulfides to Alkenes

…, AV Artem'ev, NA Belogorlova…

文献索引：Malysheva, Svetlana F.; Gusarova, Nina K.; Artem'Ev, Alexander V.; Belogorlova, Nataliya A.; Albanov, Alexander I.; Borodina, Tatyana N.; Smirnov, Vladimir I.; Trofimov, Boris A. European Journal of Organic Chemistry, 2014 , vol. 2014, # 12 p. 2516 - 2521

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被引用次数: 4

摘要

Abstract An atom-economic green synthesis of tertiary phsophine sulfides has been developed based on catalyst-and solvent-free addition of secondary phosphine sulfides to diverse terminal and internal alkenes (hept-1-ene, cyclohexene, styrenes, allyl alcohol, vinyl ethers, vinyl sulfides, vinyltrimethylsilane, 1-vinylimidazoles, vinyl acetate). The reaction proceeds under mild conditions (80 C, without solvent, 4–45 h) to afford chemo-and ...