Novel visible-light-driven catalytic carbon dioxide fixation. Synthesis of malonic acid derivatives from CO2, an. alpha.,. beta.-unsaturated ester or nitrile, and diethylzinc …
M Komatsu, T Aida, S Inoue
文献索引：Komatsu, Masashi; Aida, Takuzo; Inoue, Shohei Journal of the American Chemical Society, 1991 , vol. 113, # 22 p. 8492 - 8498
Abstract: Reaction of carbon dioxide, methacrylic esters or methacrylonitrile, and (5, 10, 15, 20-tetraphenylporphinato) aluminum methyl or ethyl took place upon irradiation with Xenon arc light (A> 420 nm), affording the corresponding (porphinato) aluminum malonate species under atmospheric pressure at ambient temperature. When diethylzinc was present in the above reaction systems,(porphinat0) aluminum ethyl was regenerated by the exchange ...
