Electrochemical synthesis of organophosphorus compounds through nucleophilic aromatic substitution: mechanistic investigations and synthetic scope

H Cruz, I Gallardo, G Guirado

文献索引：Cruz, Hugo; Gallardo, Iluminada; Guirado, Gonzalo European Journal of Organic Chemistry, 2011 , # 36 p. 7378 - 7389

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被引用次数: 12

摘要

Abstract Advantages of the electrochemical approach in the nucleophilic aromatic substitution reaction, such as (a) low cost and ready availability of reagents,(b) atom economy, and (c) high yields (approaching 100%), are applied to rationalize the (polar or radical) mechanism and to develop new greener synthetic routes for the synthesis of substituted nitroaromatic organophosphorus compounds. The nucleophiles used to study ...