Substitution reactions which proceed via radical anion intermediates. 17. Synthesis of highly branched,. beta.-arylated nitroparaffins

N Kornblum, SC Carlson, J Widmer…

文献索引：Kornblum,N. et al. Journal of Organic Chemistry, 1978 , vol. 43, # 7 p. 1394 - 1399

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被引用次数: 16

摘要

YO. NO, evidence now exists in support of the view that these are electron-transfe-processes in which radical anions and free radicals are intermediates3 When the chemistry of a, p- dinitrocumene (1) was first described it was emphasized that the p-nitro grow facilitates the displacements of eq 1; in no instance did a-nitrocumene (2) react with nucleophiles under conditions which resulted in complete reaction when a, p-dinitrocumene was employed. 2 ...