Crystalline Sodium Selenocarboxylates–synthesis and characterization

…, H Kageyama, K Takagi, K Mizoguchi…

文献索引：Kato, Shinzi; Kageyama, Hideki; Takagi, Kazutaka; Mizoguchi, Kazuaki; Murai, Toshiaki Journal fuer Praktische Chemie (Leipzig), 1990 , vol. 332, # 6 p. 898 - 910

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被引用次数: 18

摘要

Abstract A series of sodium selenocarboxylates 2 were isolated from the reaction of diacyl selenides with sodium ethanolate and characterized. A convenient preparation of the sodium salts 2 by the direct reaction of acyl chlorides with sodium selenide was also established. The salts are colourless to slightly pale yellow crystals and labile towards moisture. They readily react with alkyl iodides at room temperature to give the ...