A New Sequential Intramolecular Cyclization Based on the Boekelheide Rearrangement

A Massaro, A Mordini, A Mingardi…

文献索引：Massaro, Assunta; Mordini, Alessandro; Mingardi, Anna; Klein, Jens; Andreotti, Daniele European Journal of Organic Chemistry, 2011 , # 2 p. 271 - 279

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被引用次数: 4

摘要

Abstract Pyrrolidines and piperidines were synthesized from (aminoalkyl) pyridine N-oxides with a general and quite efficient method developed by using di-tert-butylsilyl bis ( trifluoromethanesulfonate) as a new promoter for a Boekelheide-type reaction. The use of a new Boekelheide promoter, which is compatible with amino groups, opens new perspectives in view of its application in intramolecular cyclizations.