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Liquid Triarylamines: The Scope and Limitations of Piers–Rubinsztajn Conditions for Obtaining Triarylamine–Siloxane Hybrid Materials

BA Kamino, B Mills, C Reali, MJ Gretton…

文献索引:Kamino, Brett A.; Mills, Bridget; Reali, Christopher; Gretton, Michael J.; Brook, Michael A.; Bender, Timothy P. Journal of Organic Chemistry, 2012 , vol. 77, # 4 p. 1663 - 1674

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被引用次数: 27

摘要

New liquid triarylamine–siloxane hybrid materials are produced using the Piers–Rubinsztajn reaction. Under mild conditions, liquid analogues of conventional and commonly crystalline triarylamines are easily synthesized from readily available or accessible intermediates. Using a diverse selection of triarylamines, we explored the effects of siloxane group and substitution pattern on the physical properties of these materials, and we have ...