Tetrahedron

The use of metalloids (-SiMe 3,-SnR 3) as protected carbanions: Selective activation and new cyclization processes

NH Andersen, DA McCrae, DB Grotjahn, SY Gabhe…

文献索引：Andarsen, Niels H.; McCrae, David A.; Grotjahn, Douglas B.; Gabhe, Satish Y.; Theodore, Louis J.; et al. Tetrahedron, 1981 , vol. 37, # 23 p. 4069 - 4079

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被引用次数: 28

摘要

Two aspects of organosilicon and-tin chemistry will be dealt with in this paper: the reactivity of allylmetalloids and the potential of the C-MR3 function as a protected carbanion which can be unmasked to provide synthetically useful carbon nucleophiles with the primary focus on the latter.