The preparation of 1, 2, 3, 5-dithiadiazolium chlorides from the reaction of nitrile sulphides with thiazyl chloride

…, MJ Schriver, S Zhu, MJ Zaworotko

文献索引：Bridson, John N.; Copp, Steven B.; Schriver, Melbourne J.; Zhu, Shuguang; Zaworotko, Michael J. Canadian Journal of Chemistry, 1994 , vol. 72, # 9 p. 1143 - 1153

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被引用次数: 19

摘要

Adamantyl-1, 3, 4-oxathiazol-2-one has been prepared for the first time and from it 1- adamantyl nitrile sulphide has been generated. Characterisation data are presented, including the X-Ray crystal structure of the oxathiazolone.(Crystal data for C12H15NO2S: monoclinic, space group P 21/c, a= 11.334 (2) Å, b= 7.344 (1) Å, c= 14.373 (2) Å, β= 107.74 (1)°, V= 1139.5 (3) Å3, Z= 4, R= 0.042). The planar heterocyclic ring is similar to structures ...