One-step regiospecific synthesis of allylic silanes-extension to benzylsilanes

M Lefort, C Simmonet, M Birot, G Deleris, J Dunogues…

文献索引：Lefort, Marcel; Simmonet, Christian; Birot, Marc; Deleris, Gerard; Dunogues, Jacques; Calas, Raymond Tetrahedron Letters, 1980 , vol. 21, p. 1857 - 1860

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被引用次数: 14

摘要

Abstract Allyltrichlorosilanes are prepared according to a one-step regiospecific process based on the reaction of allyl chlorides with SiCl 4 and NiCp 2/HMPA (catalyst), in the presence of industrial methylchlorodisilane fraction. 4 Benzyltrihalosilanes are similarly obtained.